段正超，男，博士，教授，碩士研究生導(dǎo)師

研究方向：不對稱催化及藥物合成

Email: [email protected]

主講課程：有機(jī)化學(xué)、藥物合成反應(yīng)、有機(jī)波譜解析

一、教育與研究經(jīng)歷

1993.09-1997.07 西南民族大學(xué)化學(xué)系，應(yīng)用化學(xué)專業(yè)，獲學(xué)士學(xué)位

1997.07-今 湖北民族大學(xué)（原湖北民族學(xué)院）化學(xué)與環(huán)境工程學(xué)院，從事教學(xué)及科研工作

2002.09-2005.09 中科院大連化學(xué)物理研究所，有機(jī)化學(xué)專業(yè)，獲理學(xué)碩士學(xué)位

2006.09-2009.12 中科院大連化學(xué)物理研究所，有機(jī)化學(xué)專業(yè)，獲理學(xué)博士學(xué)位

二、主持科研項(xiàng)目

(1) 2013.1-2016.12，新型手性P/N配體的設(shè)計(jì)合成及不對稱催化性能研究，國家自然科學(xué)基金委，50萬元

(2) 2011.1-2012.12，新型手性P/S配體的設(shè)計(jì)合成及其在不對稱催化中的應(yīng)用研究，教育部，10萬元

(3) 2011.1-2012.12，新型手性P/S配體的設(shè)計(jì)合成及其應(yīng)用研究，湖北省教育廳，2萬元

(4) 2011.1-2012.12，基于三唑雜環(huán)骨架的手性P/S配體的設(shè)計(jì)、合成及不對稱催化性能研究，湖北民族學(xué)院，2萬元

(5) 2011.1-2012.12，新型手性N,N,P三齒配體的設(shè)計(jì)合成及應(yīng)用研究，湖北民族學(xué)院，2萬元

三、主要代表性成果

1. 張華林，郭志謀，王聯(lián)芝，金高娃，鄒麗紅，呂園園，馬明輝，閆競宇*，段正超*，梁鑫淼.  基于電噴霧-四極桿-飛行時間質(zhì)譜的神經(jīng)節(jié)苷脂的結(jié)構(gòu)解析.  分析化學(xué). 2019, 47(06):  925-932.

2. Zheng-chao Duan*, Lian-zhi Wang, Xin-jian Song, Xiang-ping Hu, Zhuo Zheng. Enantioselective synthesis of optically active alkylphosphonates via Rh-catalyzed asymmetric hydrogenation of beta-substituted alfa,beta-unsaturated phosphonates. Tetrahedron:Asymmetry 2012,23, 508–514.

3. Zhengchao Duan*, Lianzhi Wang, Xiaoyu Zuo, Xiangping Hu, Zhuo Zheng. Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of beta-substituted α,β-unsaturated phosphonates.Chinese Journal of Catalysis 2014, 35, 227–231.

4. 段正超*，王聯(lián)芝，胡向平，鄭 卓.衍生于手性雙二茂鐵乙胺的單齒亞磷酰胺配體在不對稱催化氫化中的應(yīng)用.分子催化，2012,26,328-332.

5. 段正超*，王聯(lián)芝，左曉宇，屈桃李，胡向平，鄭 卓. WalPhos配體/銠配合物對β，γ-不飽和膦酸酯的不對稱催化氫化.應(yīng)用化學(xué)，2014, 31, 242-244.

6. Duan Zhengchao*, Wang Lianzhi, Qu Taoli, Zuo Xiaoyu, Hu Xiangping, Zheng Zhuo. Enantioselective Synthesis of Chiral 2-Phenylpropanol via Rh-catalyzed Asymmetric Hydrogenation of 2-Phenylprop-2-en-1-ol.應(yīng)用化學(xué)，2014, 31, 1356-1358.

7. Zheng-Chao Duan, Xiang-Ping Hu*, Dao-Yong Wang, Jia-Di Huang, Sai-Bo Yu, Jun Deng, Zhuo Zheng*. Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands.Adv. Synth. Catal.2008,350, 1979-1983.

8. Zheng-Chao Duan, Xiang-Ping Hu*, Cheng Zhang, Dao-Yong Wang, Sai-Bo Yu, Zhuo Zheng*. Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gama-Unsaturated Phosphonates with Chiral Ferrocene-based Monophosphoramidite Ligands.J. Org. Chem.2009,74, 9191-9194.

9. Zheng-Chao Duan, Xiang-Ping Hu*, Jun Deng, Sai-Bo Yu, Dao-Yong Wang, and Zhuo Zheng*.Asymmetric synthesis of chiral glutaric acid derivatives via Rh-catalyzed enantioselective hydrogenation.Tetrahedron: Asymmetry2009,20, 588-592.

10. Zheng-Chao Duan, Xiang-Ping Hu*, Dao-Yong Wang, Sai-Bo Yu, Zhuo Zheng*. Cu-catalyzed asymmetric conjugate reduction of beta-substituted alfa,beta-unsaturated phosphonates: an efficient synthesis of optically active beta-stereogenicalkanephosphonates.Tetrahedron Lett.2009,50, 6720-6722.

        11. DUAN Zhengchao, HU Xiangping, ZENG Qingheng, ZHENG Zhuo*. Enantioselective Addition of Phenylacetylene to Aldehydes Using a Planar Chiral N,O-Ferrocene Ligand.Chinese Journal of Catalysis2005,26, 352-354.